w of CH3COOH=2.5 gm
mol.wt. of CH3COOH= 12+3+12+16 x2 +1=60
w of benzene= 75 gm =0.075 kg
mol.wt. of C6H6= 12 x6 +1 x 6 =78
Molality =wt. of solute/ (mol.wt. of solute x wt. of solvent in kg)
m=2.5/60 x 0.075
m =0.56 mole /kg Ans.
(B) mole fraction
moles of CH3COOH= wt. /mol.wt =2.5/60
moles of CH3COOH=0.04
moles of C6H6= wt. /mol.wt =75/78
moles of C6H6=0.96
total moles =0.042 +0.96=1.0
mole fraction of CH3COOH = moles of CH3COOH/total moles=0.04/1 =0.04
mole fraction of C6H6 = moles of C6H6 /total moles=0.96/1 =0.96