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Question

Calculate the number of hours of service that can be derived at 1 atm and 300 K from an acetylene lamp containing 640 g of calcium carbide. Given that the lamp requires 50 L acetylene gas at 1 atm and 300 K for one hour. [Take 0.0821×300=25]

A
5 hr
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B
6 hr
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C
5.5 hr
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D
6.5 hr
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Solution

The correct option is A 5 hr
CaC2+2H2OCa(OH)2+C2H2
Number of moles of CaC2= Given mass of CaC2Molecular Mass of CaC2
= 640/64=10 mol
Since 1 mole of CaC2 produces 1 mole of C2H2
So, 10 moles of CaC2 will produce 10 moles of C2H2
According to the ideal gas equation,

PV = nRT

or
V=nRTP=10×0.0821×3001=250 L
Number of hours of service T = Total amount of Acetylene producedAmount of acetylene used per hour
T=250 L50 L/hr=5 hr

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