Calculate the number of hours of service that can be derived at 1atm and 300K from an acetylene lamp containing 640g of calcium carbide. Given that the lamp requires 50L acetylene gas at 1atm and 300K for one hour. [Take 0.0821×300=25]
A
5 hr
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B
6 hr
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C
5.5 hr
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D
6.5 hr
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Solution
The correct option is A 5 hr CaC2+2H2O→Ca(OH)2+C2H2 NumberofmolesofCaC2=GivenmassofCaC2MolecularMassofCaC2
= 640/64=10mol
Since 1 mole of CaC2 produces 1 mole of C2H2
So, 10 moles of CaC2 will produce 10 moles of C2H2
According to the ideal gas equation,
PV=nRT
or V=nRTP=10×0.0821×3001=250L Numberofhoursofservice′T′=TotalamountofAcetyleneproducedAmountofacetyleneusedperhour T=250L50L/hr=5hr