We have to find the number of molecules present in 16g of solid sulphur.
The molecular mass of the sulphur molecule is 32 × 8 = 256 u.
1 mole of sulphur molecules is equal to 256 grams.
This means 256 g of solid sulphur contains = 6.022 x 1023 molecules.
Then, 16 g of solid sulphur contains =6.022 x 1023 / 256 × 16 molecules
= 3.76375 x 1022 molecules
Therefore, 16 g of S8 contains 3.76 x 1022 molecules.