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Question

Calculate the shortest and longest wavelengths in hydrogen spectrum of Lyman series.

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Solution

For Lyman series, n1=1.
For shortest wavelength in Lyman series (i.e., series limit), the energy difference in two states showing transition should be maximum, i.e., n2=.
So, 1λ=RH[11212]=RH
λ=1109678=9.117×106cm
=911.7˚A
For longest wavelength in Lyman series (i.e., first line), the energy difference in two states showing transition should be minimum, i.e., n2=2.
So, 1λ=RH[112122]=34RH
or λ=43×1RH=43×109678=1215.7×108cm
=1215.7˚A.

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