We can write all the equations with their
△G values.
Hg2Cl2+2e−⟶2Hg+2Cl−;△G∘=−nFE∘cell=−−52110J…(1)
Hg22⟶2Hg2++2e−;△G∘=177560J…(2)
2Hg⟶Hg2+2+2e−;]triangleG∘=152470J…(3)
Cl22e−⟶2Cl−;△G∘=−262480J…(4)
Adding reaction (2) and (3) we get,
2Hg⟶2Hg2++4e−;G∘=330030⟶(5)
Adding reaction (1) and (4), we get,
Hg2Cl2+Cl2+4e−⟶4Cl−+2Hg;△G∘=−314590⟶(6)
Adding reactionn (5) and (6), we get,
Hg2Cl2+Cl2⟶2Hg++4Cl−;△G∘=540400⟶(7)
∴E∘cell=△G∘nF=154404×96500=0.04V