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Question

Calculate the volume occupied by 14.0 g N2 at 200 K and 8.21 atm pressure if PcVcRTc=38 and PrVrTt=2.2
[write the value to the nearest integer]

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Solution

14gN20.5mole
T=200k,P=8.21atm
PcVcRTc=38,PrVrTr=2.2
Pr=PPc,Vr=VVc,Tr=T/Tc SO,
(PcPr)(VcVr)R(TcTr)=38×2.2PVRT=32×2.2
V=38×2.2×0.0821×2008.21=1.65L
so volume of 0.5 mole N2 (0.5 250 N2 5 5:)=1.65×0.5=0.825L

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