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Question

Calculate the volume of 0.1M naOH solution required to neutralise the solution produced by dissolving 1.1g of P4O6 in water

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Solution

P4O6 + 6 H2O 4 H3PO34 H3PO3 8 H+ + 4 HPO32- (since H3PO3 is a diprotic acid)Molar mass of P4O6 = 220 gFrom the equations we come to know that 220 g of P4O6 give 8 H+ which need8 NaOH for its neutralisation.1.1 g of P4O6 = 8220 × 1.11 = 0.04 mole of NaOH0.04 mole of NaOH = 0.04 L of 1 M NaOH = 0.4 L of 0.1 M NaOHThus the volume of NaOH = 0.4 L = 400 ml

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