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Question

Calculate the volume of hydrogen liberated at 27C and 760 mm pressure by treating 1.2 g of magnesium with excess of hydrochloric acid.

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Solution

The balanced equation is:
Mg+2Hclmgcl2+H2
1 mol 1 mol
24g 22.4 liter at NTP
24 g of mg liberate hydrogen= 22.4 liter
1.2 g mg will liberate hydrogen
22.424×1.2=1.12 liter
the volume of hydrogen under given condition can be calculated
by applying
P1V1T1=P2V2T2
P1=760mm
T1=273K
V1=1.12 liter
P2=760 mm
T2=(27+273)=300K
V2=?
V2=760×1.12273×300760=1.2308

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