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Question

Calculate the work done in an open vessel at 300 K, when 168 g iron having molar mass 56 g/mol reacts with dil.HCl
R2 cal/mol K

A
1200 cal
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B
1400 cal
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C
1800 cal
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D
2400 cal
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Solution

The correct option is C 1800 cal
Fe+2HClFeCl2+H21 mol 1 mol16856=3 mol 3 molNow,V2=VH2and V1=0
(For solid + liquid state)
Work done (W)=p(v2v1)W=p(H20)W=pVH2W=nH2RTW=3×2×300W=1800 cal

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