Calculate the work done when 2moles of hydrogen expand isothermally and reversibly at 25∘C from 15to45litres.
A
−1309calories
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B
−14.36calories
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C
−2872calories
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D
−28.72calories
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Solution
The correct option is A−1309calories Work done in an isothermal reversible process is given as, w=−2.303nRTlogV2V1
Given : V1=15L V2=45L n=2mol R=2cal/K.mol T=298K
So, w=−2.303×2×2×298×log4515 w=−2745.1×log3 w=−1309.7cal