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Question

Calculate the work done when one mole of gas is allowed to expand freely in vacuum?

A
20 J
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B
0 J
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C
10 J
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D
None of the above
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Solution

The correct option is B 0 J
Gas expands in vacuum, so it is a case of free expansion i.e., Pext=0 and thus, it is an irreversible process.
Therefore, W=Pext(V2V1)=0
In free expansion, the gas is expanding in vaccuum and the molecules move freely i.e the gas expands against no force.

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