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Byju's Answer
Standard XII
Chemistry
Percentage Composition
Calculate w a...
Question
Calculate w and
△
U
for the conversion of 1 mol of water at
100
0
C
to steam at 1 atm pressure. Heat of vaporization of water at
100
0
C
is 40.670 kJ
m
o
l
−
1
. Assume ideal gas behavior.
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Solution
H
2
O
(
l
)
⇌
H
2
O
(
g
)
P
=
1
a
t
m
w
.
d
=
△
n
g
a
s
R
T
(at constant
P
)
=
(
1
×
8.314
×
373
)
J
=
3101.122
J
≈
3.1
k
J
△
U
=
△
H
v
a
p
+
w
(
1
s
t
law of
T
D
)
=
3.1
k
J
+
40.67
k
J
=
43.77
k
J
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Similar questions
Q.
If water vapour is assumed to be a perfect gas, molar enthalpy change for vapourization of 1 mol of water at 1 bar and
100
0
C
is
41
k
J
.
m
o
l
−
1
. Calculate the internal energy change, when
1 mol of water is vaporized at 1 bar pressure and
100
0
C
.
Q.
The molar enthalpy change for
H
2
O
(
1
)
⇌
H
2
O
(
g
)
at
373
K and
1
atm is
41
kJ/mol. Assuming ideal behavior, the internal energy change for vaporization of
1
mol of water at
373
K and
1
atm in kJ
m
o
l
−
1
is
?
Q.
The molar enthalpy change for
H
2
O
(
l
)
⇌
H
2
O
(
g
)
at
373
K and
1
atm is
41
k
J
/
m
o
l
. Assuming ideal behavior, the internal energy change for vaporization of
1
mol of water at
373
K
and
1
atm in kJ mol
−
1
is:
Q.
Calculate work done
w
for the conversion of
0.5
moles of water at
100
∘
C
to steam at
1
a
t
m
pressure. Heat of vaporisation of water at
100
∘
C
is
40670
J
m
o
l
−
1
Q.
Calculate
w
and
Δ
U
for the conversion of
0.5
mole of water at
100
o
C
to steak at
1
atm pressure. Heat of vaporisation of water at
100
o
C
is
40670
J
m
o
l
−
1
.
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