Can pcc convert p nitrotoluene to p nitrobenzaldehyde

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Convert

(i) 3-Methylaniline into 3-nitrotoluene.

(ii) Aniline into 1,3,5-tribromobenzene.

How will you convert benzene into

(i) p-nitrobromobenzene (ii) m-nitrochlorobenzene

(iii) p -nitrotoluene (iv) acetophenone

How will you convert benzene into
(i) p-nitrobromobenzene

(ii) m-nitrochlorobenzene

(iii) p -nitrotoluene

(iv) acetophenone

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