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Question

CaOCl2 in aqueous solution changes to Cl2. What is the average oxidation state of Cl in CaOCl2?

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Solution

The oxidation number of chlorine in CaOCl2 (bleaching powder) In bleaching powder, Ca(OCl)Cl, the two Cl atoms are in different oxidation states i.e., one Cl having oxidation number of 1 and the other as OCl having oxidation number of +1.

Therefore, the average oxidation state of chlorine is 0.

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