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Question

Carbene in the singlet state has one lone pair of electrons. Among the dihalocarbenes in the singlet state:

A
CF2 is the most stable singlet carbene which is a ambiphile
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B
CBr2 is the most stable singlet carbene which is a ambiphile
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C
CF2 is the most stable singlet carbene which is an electroplate
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D
CBr2 is the most stable singlet carbene which is an electroplate
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Solution

The correct option is C CF2 is the most stable singlet carbene which is an electroplate
Carbene and dihalocarbenes are electron deficient. They are electrophilic in nature. Dihalocarbenes such as CF2CCl2 and CBr2 exist in singlet state CF2 involves back donation. Hence it is the most stable carbene.

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