Carbon-14 is used to determine the age of organic material. The procedure is based on the formation of 14C by neutron capture in the upper atmosphere.
147N+10n→146C+1P1
14C is absorbed by living organisms during photosynthesis. The 14C content is constant in living organisms once the plant or animal dies, the uptake of carbon dioxide by it ceases and the level of 14C in the dead being, falls due to the decay which C-14 undergoes 146C→147N+β−
The half-life period of 14Cis5770yr.
The decay constant (λ) can be calculated by using the following formula λ=0.693t12.
The comparison of the β− activity of the dead matter with that of the carbon still in circulation
enables measurement of the period of the isolation of the material from the living cycle. The
method however, ceases to be accurate over periods longer than 30,000 yr. The proportion of 14C to
12C in living matter is 1:1012.
What should be the age of fossil for meaningful determination of its age?
Fossil whose age is closest to half-life of C-14 (5770 yr) will yield the most accurate age by C-14 dating.