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Question

Carbon can reduce ferric oxide to iron at a temperature above 983 K because:

A
carbon monoxide formed is thermodynamically less stable than ferric oxide
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B
carbon has a higher affinity towards oxidation than iron
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C
free energy change for the formation of carbon dioxide is less negative than that for ferric oxide
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D
iron has a higher affinity towards oxygen than carbon
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Solution

The correct option is B carbon has a higher affinity towards oxidation than iron
Above 983 K, free energy change for the formation of CO2 is more negative than that for ferric oxide. Thus, above this temperature, carbon has a higher affinity towards oxidation than iron.

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