Carbon-carbon double bond length will be maximum in which of the following compounds?
A
CH3−CH=CH2
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B
CH3−CH=CH−CH3
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C
CH3−C|=CH3C|−CH3CH3
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D
CH2=CH2
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Solution
The correct option is CCH3−C|=CH3C|−CH3CH3 Due to hyperconjugation by methyl group the double bond is partially shared as shown. Therefore more no of hyperconjugation means more bond sharing and hence less double bond character and therefore longer bond. Therefore option (C) is correct as it contains maximum hyperconjugation.