Carbon, silicon and germanium have four valence electrons each. These are characterised by valence and conduction bands separated by energy band gap respectively equal to (Eg)C, (Eg)Si and (Eg)Ge. Which of the following statements is true? (a) (Eg)Si < (Eg)Ge < (Eg)C
(b) (Eg)C< (Eg)Ge > (Eg)Si
(c) (Eg)C> (Eg)Si > (Eg)Ge
(d) (Eg)C= (Eg)Si = (Eg)Ge
It is given that the carbon, silicon and germanium atoms have four valence electrons, the energy band gap of carbon, silicon and germanium is (Eg)C, (Eg)Si and (Eg)Ge respectively.
The energy band gap of carbon is maximum and the energy band gap of germanium is minimum among all.
So, the correct order of the energy band gap is,
(Eg)C> (Eg)Si > (Eg)Ge
Hence, the correct statement is (c).