Carbylamine test is performed in the presence of KOH by heating a mixture of:
A
an alkyl halide and a primary amine
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B
chloroform and silver powder
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C
an alkyl cyanide and a primary amine
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D
tri-halogenated methane and a primary amine
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Solution
The correct option is D tri-halogenated methane and a primary amine Carbylamine reaction is used for test of primary amines, in this reaction isocyanide forms.
The reaction of the process is: C6H5−NH2+CHCl3+3KOH→C6H5NC+3KCl+3H2O