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Question

CCl4 and acetone form a non-ideal solution at room temperature in a copper container. For this process the true statement(s) is/are:

A
ΔG is positive
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B
ΔSsystem is positive
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C
ΔSsurrounding<0
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D
ΔH>0
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Solution

The correct options are
B ΔSsystem is positive
C ΔSsurrounding<0
D ΔH>0
ΔG=ve,ΔSsystem=+ve Always for solution formation.
ΔSsurr.<0 Heat absorbed by solution from surrounding.
ΔH>0 For this solution as CCl4 is non-polar but acetone is polar.

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