In the first oxide, oxygen = 43.7 parts by mass
thus element X = 100 - 43.7 = 56.3 parts by mass
As the formula of the oxide is X4O6 , this means
56.3 parts by mass of element X = 4 atoms of element X
and 43.7 parts of oxygen = 6 atoms of oxygen
In the second oxide,
oxygen = 56.3 parts by mass
element X = 100 - 56.3 = 43.7 parts
But 56.3 parts by mass of element= 4 atoms of element
thus 43.7 parts of element = atoms of element = 3.10 atoms of element
Also 43.7 parts by mass of oxygen = 6 atoms of oxygen
thus 56.3 parts by mass of oxygen = atoms of oxygen = 7.73 atoms of oxygen
Hence ratio of X : O in the second oxide
3.10 : 7.73
= 3.10/3.10 : 7.73/3.10
= 1 : 2.5
= 2 : 5
Therefore formula of second oxide = X2O5