Synthesis of Aldehydes and Ketones Using Carboxylic Acid and Its Derivatives
CH 3COCl + H...
Question
CH3COCl + H2(A)−−→ (B)
The given reaction is an example of Rosenmund's reaction. Identify the product B:
A
Formaldehyde
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B
cloroethane
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C
Acetaldehyde
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D
Ethanol
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Solution
The correct option is B Acetaldehyde
The compound (C) is acetaldehyde CH3CHO. In Rosenmund's reaction, acid chloride (such as acetyl chloride) reacts with hydrogen in the presence of Pd / BaSO4 / quinoline to formaldehyde (such as acetaldehyde).