CH3-O-C-CH3 CH3-O-C-CH3 - X3C-O-C-CX3The trihaloketone also undergoes hydrolysis in present of OH forming CH3-O-C-CH3 CH3-O-C-O-CHX3During formation of trihaloketone- which halogen is introduced most easily-

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Bromine Water Test

CH3-O||C-CH3 ...

Question

$C H_{3} - O | | C - C H_{3}$ $X_{2}, O H^{-} - ---- \to$ $C H_{3} - O | | C - C H_{3}$

$\to X_{3} C - O | | C - C X_{3}$

The trihaloketone also undergoes hydrolysis in present of OH forming

$C H_{3} - O | | C - C H_{3}$ $O H^{-} - -- \to$ $C H_{3} - O | | C - O^{-} - C H X_{3}$

During formation of trihaloketone, which halogen is introduced most easily?

First

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C H_{3} - O | | C - C H_{3}

X_{2}, O H^{-} - ---- \to

C H_{3} - O | | C - C H_{3}

\to X_{3} C - O | | C - C X_{3}

C H_{3} - O | | C - C H_{3}

O H^{-} - -- \to

C H_{3} - O | | C - O^{-} - C H X_{3}

C H_{3} - O | | C I - C H_{3}

C H_{3} - O | | C I I - C l

C H_{3} - O | | C I I I - N H_{2}

C H_{3} - O | | C I V - O H

C H_{3} - O | | C - O V - O | | C - C H_{3}

C H_{2} = O H | C - C H_{2} - O | | C - C H_{3} ⇌ C H_{3} - O | | C - C H_{2} - O | | C - C H_{3} ⇌ C H_{3} - O H | C = C H - O | | C - C H_{3}

I

I I

I I I

C H_{2} = O H | C - C H_{2} (I) - O | | C - C H_{3} ⇌ C H_{3} - O | | C - C H_{2} (I I) - O | | C - C H_{3}

⇌ C H_{3} - O H | C = C H (I I I) - O | | C - C H_{3}

C H_{3} - C | | O - C H_{3} I C H_{3} - C | | O - C | | O - C H_{3} I I C H_{3} - C | | O - C H_{2} - C | | O - C H_{3} I I I

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