wiz-icon
MyQuestionIcon
MyQuestionIcon
4
You visited us 4 times! Enjoying our articles? Unlock Full Access!
Question

CH3CH2OH can be converted into CH3CHO by . . . .
(a) catalytic hydrogenation
(b) treatment with LiAIH4
(c) treatment with pyridinium chlorochromate
(d) treatment with KMnO4

Open in App
Solution

Ethanal (CH3CHO) is an oxidised product of ethanol. Pyridinium chlorochromate (C5H5+NHClCrO3) oxidises primary alcohols to aldehydes. Strong oxidising agents such as KMnO4 are used for getting carboxylic acid from alcohols.
The oxidation process can be stopped at the aldehyde stage if Cr(VI) reagents such as Collin's reagent (CrO3.2C5H5N), Corey's reagent or pyridinium chlorochromate and pyridinium dichromate [(C5H5NH2)2+Cr2O27] in anhydrous medium are used as the oxidising agent. So, the correct option is (c).
CH3CH2OHEthanolPCC−−CH3CHOEthanol


flag
Suggest Corrections
thumbs-up
1
Join BYJU'S Learning Program
similar_icon
Related Videos
thumbnail
lock
Chemical Properties of Alcohols 1
CHEMISTRY
Watch in App
Join BYJU'S Learning Program
CrossIcon