Chemiosmotic theory
According to the chemiosmotic theory of ATP generation, ATP is generated utilizing the electrochemical gradient generated due to the accumulation of protons in the thylakoid lumen of chloroplast or peri-mitochondrial space in mitochondria.
The accumulation of protons gives rise to an electric gradient, due to the accumulation of positive charge and a chemical gradient due to the accumulation of hydrogen atom.
When protons move along this electrochemical gradient through F0−F1, ATP synthase enzyme complex, ATP generation occurs.