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Question

Chlorination of methane proceeds by:

A
electrophilic substitution
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B
nucleophilic substitution
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C
free radical substitution
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D
none of these
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Solution

The correct option is D free radical substitution
CH4X2/hv−−−−−520670KCH3X+HXX2/hv−−−−−520670KCH2X2+HXX2/hv−−−−−520670KCHX3+HXX2/hv−−−−−520670KCX4+HX
Chlorination of methane proceeds by Free radical substitution. It is not possible to control the reaction at mono-substitution level. A mixture of products is obtained.

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