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Question

Chlorine atom in its third excited state with fluorine to form a compound X. The formula and shape of X are:

A
ClF5, pentagonal
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B
ClF4, tetrahedral
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C
ClF4, pentagonal bipyramidal
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D
ClF7, pentagonal bipyramidal
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Solution

The correct option is D ClF7, pentagonal bipyramidal
From the diagram, it is clear that chlorine has 7 unpaired orbitals each of which can form a bond with fluorine. Hence, hybridization is sp3d3 and shape is pentagonal bipyramidal.
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