Chlorine exists in two isotopic forms, Cl−37 and Cl−35 but its atomic mass is 35.5. This indicates the ratio of Cl−37 and Cl−35 is approximately:
A
1:2
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B
1:1
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C
1:3
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D
3:1
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Solution
The correct option is C1:3
Let relative abundance of Cl-37 be A1% with mass M1=37 amu
∴ The relative abundance of Cl-35 = A2% with mass, M2=35 amu
where A1+A2=100
Thus A2%=(100−A1)%
Using average atomic mass, Mavg=M1A1+M2A2A1+A2
Mavg=37×A1+35×(100−A1)A1+(100−A1)=2A1+3500100
Given that: Mavg=35.5
∴2A1+3500100=35.5
2A1=35.5×100−3500=50
A1=502=25and A2=100−A1=100−25 =75
Thus the ratio of isotope abundance of Cl−37toCl−35 is A1:A2=25:75=1:3