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Question

Chlorine reacts with hot and concentrated NaOH and produces compounds (X) and (Y). Compound (X) gives white precipitate with silver nitrate solution. The average bond order between Cl and O atoms in (Y) is t; find 3t.

A
5.0
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B
5
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C
5.00
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Solution

3Cl2+6NaOHConc.5NaCl+NaClO3+3H2O
Ag+ forms precipitate with Cl i.e. AgCl.
AgClO3 is soluble.
X is NaCl
Y is NaClO3
Now, structure of ClO3 is

Bond order is 53t=53
3t=5

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