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Question

Chloroform reacts with oxygen in the presence of light to give:

A
carbon tetrachloride
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B
carbonyl chloride
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C
methyl chloride
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D
methylene dichloride
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E
acetaldehyde
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Solution

The correct option is A carbonyl chloride
Chloroform reacts with oxygen in the presence of light to give a poisonous compound carbonyl chloride, which is also known by the name phosgene.
CHCl3+12O2hvCOCl2Carbonyl chloride(poisonous)+HCl
That's why chloroforms generally stored in dark coloured bottles filled upto brim.

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