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Question

Choose the correct answer form the alternatives given.
All alkali halides are soluble in water except LiF. The low solubility of LiF in water is due to its ______(i) the low solubility of CsI is due to ______(ii). LiF is soluble in ______(iii) solvents.

A
(i)-low lattice enthalpy (ii)-large hydration enthalpy (iii)-polar solvents
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B
(i)-high lattice enthalpy (ii)-smaller hydration enthalpy (iii)-non-polar solvents
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C
(i)-high hydration enthalpy (ii)-high lattice enthalpy (iii)-non-polar solvents
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D
(i)-smaller high hydration enthalpy (ii)-lattice enthalpy (iii)-polar solvents
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Solution

The correct option is B (i)-high lattice enthalpy (ii)-smaller hydration enthalpy (iii)-non-polar solvents
The low solubility of LIF in water is due to its high lattice enthalpy whereas the low solubility of CsI is due to smaller hydration enthalpy of two large size ions. LIF is soluble in non-polar solvents like ethanol, acetone, etc.

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