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Test for Ammonia

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Choose the correct answer:
The salt which in solution gives a pale green precipitate with sodium hydroxide solution and a white precipitate with barium chloride solution is:
A. Iron (III) sulphate
B. Iron (II) sulphate
C. Iron (II) chloride
D. Iron (III) chloride

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Solution

B. Iron (II) sulphate

The salt that gives a pale-green precipitate with sodium hydroxide solution, and a white precipitate with barium chloride solution is iron (II) sulphate.

FeSO₄ + 2NaOH → Fe(OH)₂ + Na₂SO₄
Pale Green precipitate
FeSO₄ + BaCl₂ → BaSO₄ + FeCl₂
White precipitate

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The salt which in solution gives a pale green precipitate with sodium hydroxide solution and a white precipitate with barium chloride solution is:

Q. (a) Sodium hydroxide solution can be used to distinguish between (i) Iron (II) sulphate solution and (ii) iron (III) sulphate solution; because these solutions give different coloured precipitates with sodium hydroxide solution. Give the colour of the precipitate formed with each of the solution.
(b) What will you observe when barium chloride solution is added to iron (II) sulphate solution?
(c) How will the action of dilute hydrochloric acid on sodium carbonate and sodium sulphite enables you to distinguish between these two compounds?

Q. The questions (i) to (v) refer to the following salt solutions listed (a) to (f):
(a) Copper nitrate
(b) Iron (II) sulphate
(c) Iron (III) chloride
(d) Lead nitrate
(e) Magnesium sulphate
(f) Zinc chloride

(i) Which two solutions will give a white precipitate when treated with dilute hydrochloric acid followed by barium chloride solution?
(ii) Which two solution will give a white precipitate when treated with dilute nitric acid followed by silver nitrate solution?
(iii) Which solution will give a white precipitate when either dilute hydrochloric acid or dilute sulphuric acid is added to it?
(iv) Which solution becomes a deep/inky blue colour when excess of ammonium hydroxide is added to it?
(v) Which solution gives a white precipitate with excess ammonium hydroxide solution?

Q. Using sodium hydroxide solution, how would you distinguish:
(a) Ammonium sulphate from sodium sulphate.
(b) Zinc nitrate solution from calcium nitrate solution.
(c) Iron (II) chloride from Iron (III) chloride.

Q. Sodium sulphate solution gives blue precipitate with barium chloride solution.

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