The correct option is A (a)-iv-IV
Benzil-benzilic acid rearrangement:
Substrate - 1,2-Diketone
Reagent - NaOH/H+
Product - α-Hydroxy carboxylic acid
HVZ reaction:
Substrate - Carboxylic acid
Reagent - Red P/X2 and H2O
Product - α-Halo carboxylic acid
Haloform reaction:
Substrate - Methyl ketone
Reagent - X2 in NaOH
Product - Sodium salt of carboxylic acid + Haloform
Gabriel phthalimide reaction:
Substrate - Phthalimide
Reagent - Alc. KOH, RX, NaOH(aq)
Product - Primary amine