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Question


Choose the correct combination:

A
(a)-iv-IV
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B
(b)-i-II
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C
(c)-iii-III
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D
(d)-ii-III
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Solution

The correct option is A (a)-iv-IV

Benzil-benzilic acid rearrangement:
Substrate - 1,2-Diketone
Reagent - NaOH/H+
Product - α-Hydroxy carboxylic acid


HVZ reaction:
Substrate - Carboxylic acid
Reagent - Red P/X2 and H2O
Product - α-Halo carboxylic acid

Haloform reaction:
Substrate - Methyl ketone
Reagent - X2 in NaOH
Product - Sodium salt of carboxylic acid + Haloform

Gabriel phthalimide reaction:
Substrate - Phthalimide
Reagent - Alc. KOH, RX, NaOH(aq)
Product - Primary amine

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