Choose the correct option(s) regarding synergic bond:
A
It is formed by the back donation of a metal atom/ion to the ligand.
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B
The internal bond length of a ligand and the metal-ligand bond length does not vary due to the synergic bonding.
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C
It is a σ-bond formed between a metal atom/ion and a ligand.
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D
All of the above.
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Solution
The correct option is A It is formed by the back donation of a metal atom/ion to the ligand. Synergic Bond:
The pi-bond formed between a metal atom/ion and a ligand by back donation of a metal atom/ion is known as a synergic bond.
The internal bond length of a ligand and the metal-ligand bond length varies due to the synergic bonding, and this effect is known as synergic effect.
Synergic effect is due to a self-strengthening bond, which involves transference of electrons from
Ligand to metal
Metal’s filled orbitals to vacant orbitals of ligand