Choose the correct statement among the following for the product formed, when cis-2-butene is reacted with bromine in CCl4.
A
Number of the stereoisomers of the product formed are 2, namely d-2,3-dibromobutane and l-2,3-dibromobutane
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B
Number of the stereoisomers of the product formed are 2,namely D-2,3-dibromobutane and L-2,3-dibromobutane
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C
Three stereoisomers of the product are possible, d,l and meso
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D
Number of the stereoisomers of the product formed are4, namely d-2,3-dibromobutane, l-2,3-dibromobutane, d-2,2-dibromobutane, l-2,2-dibromobutane.
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Solution
The correct option is A Number of the stereoisomers of the product formed are 2, namely d-2,3-dibromobutane and l-2,3-dibromobutane Halogens like Br, Cl and I add up to alkenes to form vicinal dihalides. Addition of halogens to alkenes is an example of electrophilic addition reaction. Addition of two substituents to multiple bonded C atoms from the opposite sides of the multiple bond is known as anti-addition.
When anti addition takes place to a symmetrical cis alkene or unsymmetrical alkene (both cis and trans), then racemic mixture is formed.