Choose the correct statement(s) for the following compounds :
A
Compound (a) does not show tautomerism.
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B
Compound (b) shows tautomerism
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C
Compound (d) has a stable enol form
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D
Compound (c) does not show tautomerism
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Solution
The correct option is D Compound (c) does not show tautomerism Tautomerism is a phenomenon where a single compound tends to exist in two or more structures which are interconvertible and differ in the relative position of one atomic nucleus.
In Keto-enol tautomerism, delocalisation takes place between a >C=O group and an alpha H where the equilibrium lies between a keto form and an enol form.
Here, compounds (a) , (b) and (c) do not have a enol form due to absence of H-atom on the carbon adjacent to carbonyl group.
For (d) , enol form :
It is planar , all C atoms are sp2 hybridised.
Has conjugation
Follows Huckel's rule (4n+2)e− , since it has 2πe−
Hence, highly stable due to aromaticity.