The correct options are
C If the earth did not have atmosphere , it would become intolerably cold
D It is impossible to construct a heat engine of 100 % efficiency
Good reflectors are bad absorbers of radation, and the ratio of emissive and absorptive is a constant. Hence a good reflector would be a bad emitter of radiation. Hence option A is wrong.
The burns caused by steam at 100∘C would cause a larger burns than that of water at 100∘C because of higher kinetic energy of the particles. Hence option B is wrong.
If the earth did not have an atmosphere, the heat absorbed by the suns radiation would be a lot lesser and hence it would become intolerably cold. Hence option C is true.
From the second law of thermodynamics, we know that it is impossible to make the perpetual motion machine of the first kind. In other words, a machine with 100% efficiency. Hence option D is correct.