ClO3−+Cl−→Cl2+ClO2 Which of the following is correct for this reaction:
A
Its a disproportion reaction
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B
Cl is both oxidised and reduced
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C
Cl is both reducing and oxydising agent
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D
All of these
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Solution
The correct option is D All of these The given reaction is disproportion reaction as Cl in the reaction is oxidized as well as reduced. Disproportionation is a specific type of redox reaction in which an element from a reaction undergoes both oxidation and reduction to form two different products.
In the reaction the oxidation state of Cl in ClO3− is +5 which is decreasing to either 0 in Cl2 or +4 in ClO2. Means Cl is reduced and acting as oxidizing agent.
And the oxidation state of Cl in Cl− is −1 which is increasing to either 0 in Cl2 or +4 in ClO2. Means Cl is oxidized and acting as reducing agent.