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Question

[Co(H2O)6]3+ complex is:

A
high spin complex
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B
having d2sp3-hybridization
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C
low spin complex
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D
having octahedral structure
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Solution

The correct options are
B having d2sp3-hybridization
C low spin complex
D having octahedral structure
[Co(H2O)6]3+
Co is in +3 oxidation state.
Co3+[Ar]3d6
H2O is a strong field ligand for Co3+ so it will pair the electrons in 3d orbiitals.
Hence the hybridization involved is d2sp3

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