[Co(NH3)5(NO2)](NO3)2 CAN EXHIBIT HOW MANY AND WHICH TYPE OF ISOMERISM ?

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Solution

A pair of optical isomers: It can also show linkage isomerism. It can also show ionization isomerism.

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[C o (N H_{3})_{5} (N O_{2})] (N O_{3})_{2}

Indicate the types of isomerism exhibited by the following complexes and

draw the structures for these isomers:

[C o (N H_{3})_{5} N O_{2}] C l_{2}

e n = H_{2} H C H_{2} C H_{2} N H_{2}

	List I		List II
A	$[C r {({N H}_{3})}_{4} {C l}_{2}] C l$	1	Paramagnetic and exhibits ionization isomerism
B	$[T i {(H_{2} O)}_{3} C l] {({N O}_{3})}_{2}$	2	Diamagnetic and exhibits cis-trans isomerism
C	$[P t (e n) (N H_{3}) C l] {N O}_{3}$	3	Paramagnetic and exhibits cis-trans isomerism
D	$[C o {({N H}_{3})}_{4} {({N O}_{3})}_{2}] {N O}_{3}$	4	Diamagnetic and exhibits ionization isomerism

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