Collector used in froth floatation process is :
Ethyl xanthate
Explanation for the correct options:
b) Ethyl xanthate
Explanation for the incorrect options:
a) Methyl xanthate
It fails to absorb polar groups from ores grains properly, so it is not used as a collector.
c) Xanthyl methanoate
It is utilised in the tea and coffee decaffeination process, and not as a collector.
d) Ethyl methyl xanthate:
It is not used as a collector.
Hence, option (b) is correct. Ethyl xanthate is the collector used in froth floatation process.