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Question

Color of Cd2[Fe(CN)6] is bluish white.

A
True
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B
False
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Solution

The correct option is B False
The given statement is False.
Cd2[Fe(CN)6] is white or colorless.
2Cd2++K4[Fe(CN)6]Cd2[Fe(CN)6]+4K+
Cyanide ion is strong field ligand. Hence, it forms low spin complex.
Fe2+ has 3d6 outer electronic configuration with all electrons paired. Hence, it is colorless.

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