Column-1 represents the formula of the complex- Column-2 represents the hybridization state of the complex and Column-3 represents the nature of the complex- beginarray - - hline - -Column I- - -Column 2 - Column 3 3 1 lhlineI - - Ni CO - 4- - i - sp - 3 - P -Diamagnetic High spin 11 hline III - Ni CO - 4- - iii - dsp - 2 - R - Diamagnetic - Low spin 11 hline IV - K - 2- Co CN - 4- - iv - d - 2 sp - 3 - S - ParamagneticLow spin Hhlineend array Which of the following set is correct for a diamagnetic tetrahedral complex-A- III i RB- I i PC- II i RD- III ii S

You visited us 1 times! Enjoying our articles? Unlock Full Access!

Coordination and Oxidation Number

Column-1 repr...

Question

Column-1 represents the formula of the complex.
Column-2 represents the hybridization state of the complex and
Column-3 represents the nature of the complex.
$\begin{matrix} C o l u m n I & C o l u m n 2 & C o l u m n 3 (I) & [N i (C O)_{4}] & (i) & s p^{3} & (P) & D i a m a g n e t i c (H i g h s p i n) (I I) & [P t C l_{4}]^{2 -} & (i i) & s p^{3} d^{2} & (Q) & P a r a m a g n e t i c (H i g h s p i n) (I I I) & [N i (C O)_{4}] & (i i i) & d s p^{2} & (R) & D i a m a g n e t i c (L o w s p i n) (I V) & K_{2} [C o (C N)_{4}] & (i v) & d^{2} s p^{3} & (S) & P a r a m a g n e t i c (L o w s p i n) \end{matrix}$
Which of the following set is correct for a diamagnetic tetrahedral complex?

(III) (i) (R)

Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses

(I) (i) (P)

No worries! We‘ve got your back. Try BYJU‘S free classes today!

(II) (i) (R)

No worries! We‘ve got your back. Try BYJU‘S free classes today!

(III) (ii) (S)

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Open in App

Solution

The correct option is A (III) (i) (R)
In $K_{4} N i (C O)_{4}$ Ni is in ground state i.e. $3 d^{8} 4 s^{2}$ . While CO is a strong field ligand due to which the configuration of central atom becomes $3 d^{10} 4 s^{0}$ .

The 4s and 4p orbitals get hybridized to produce $s p^{3}$ orbitals.

Suggest Corrections

Similar questions

Column-1 represents the formula of the complex.
Column-2 represents the hybridization state of the complex and
Column-3 represents the nature of the complex.
$\begin{matrix} C o l u m n I & C o l u m n 2 & C o l u m n 3 (I) & K_{4} [N i (C O)_{4}] & (i) & s p^{3} & (P) & D i a m a g n e t i c (H i g h s p i n) (I I) & [P t C l_{4}]^{2 -} & (i i) & s p^{3} d^{2} & (Q) & P a r a m a g n e t i c (H i g h s p i n) (I I I) & [N i (C O)_{4}] & (i i i) & d s p^{2} & (R) & D i a m a g n e t i c (L o w s p i n) (I V) & K_{2} [C o (C N)_{4}] & (i v) & d^{2} s p^{3} & (S) & P a r a m a g n e t i c (L o w s p i n) \end{matrix}$
Which of the following sets show Jahn-Teller effect?

Q. Column-1 represents the formula of the complex.
Column-2 represents the hybridization state of the complex and
Column-3 represents the nature of the complex.

\begin{matrix} C o l u m n I & C o l u m n 2 & C o l u m n 3 (I) & [N i (C O)_{4}] & (i) & s p^{3} & (P) & D i a m a g n e t i c (H i g h s p i n) (I I) & [P t C l_{4}]^{2 -} & (i i) & s p^{3} d^{2} & (Q) & P a r a m a g n e t i c (H i g h s p i n) (I I I) & [N i (C O)_{4}] & (i i i) & d s p^{2} & (R) & D i a m a g n e t i c (L o w s p i n) (I V) & K_{2} [C o (C N)_{4}] & (i v) & d^{2} s p^{3} & (S) & P a r a m a g n e t i c (L o w s p i n) \end{matrix}

Which of the following set is correct for a diamagnetic tetrahedral complex?

Q. Column-1 represents the formula of the complex.
Column-2 represents the hybridization state of the complex and
Column-3 represents the nature of the complex.

\begin{matrix} C o l u m n I & C o l u m n 2 & C o l u m n 3 (I) & K_{4} [N i (C O)_{4}] & (i) & s p^{3} & (P) & D i a m a g n e t i c (H i g h s p i n) (I I) & [K_{4} [F e (C N)_{6}] & (i i) & s p^{3} d^{2} & (Q) & P a r a m a g n e t i c (H i g h s p i n) (I I I) & [N i (C O)_{4}] & (i i i) & d s p^{2} & (R) & D i a m a g n e t i c (L o w s p i n) (I V) & K_{2} [C o (C N)_{4}] & (i v) & d^{2} s p^{3} & (S) & P a r a m a g n e t i c (L o w s p i n) \end{matrix}

Which set corresponds to a complex with a CFSE of

- 2.4 Δ_{0} + 2 P

Q. Column 1, 2 and 3 contains starting material, formula of the product and structure of the product respectively.

\begin{matrix} C o l u m n 1 & C o l u m n 2 & C o l u m n 3 (I) & N H_{4} N O_{3} Δ - \to & (i) & H_{3} P O_{3} & (P) & A n g u l a r (I I) & W h i t e P_{4} + a l k a l i \to & (i i) & N_{2} O & (Q) & T e t r a h e d r a l (w i t h o n e - O H) (I I I) & P b (N O_{3})_{2} 673 K - -- \to & (i i i) & H_{3} P O_{2} & (R) & T e t r a h e d r a l (w i t h t w o - O H) (I V) & P_{2} O_{3} + H_{2} O \to & (i v) & N_{2} O_{2} & (S) & L i n e a r \end{matrix}

The correct set which is representing the colourless gas neutral in nature?

Column-I-Compound, Column-II-Oxidation state, Column-III-Type of linkage

$\begin{matrix} C o l u m n 1 & C o l u m n 2 & C o l u m n 3 (I) & N a_{2} S_{2} O_{3} & (i) & + 5 & (P) & S - O - S (I I) & N a_{2} S_{4} O_{6} & (i i) & - 2 & (Q) & S - S (I I I) & H_{2} S_{2} O_{7} & (i i i) & + 6 & (R) & - (O - O) - (I V) & H_{2} S_{2} O_{8} & (i v) & + 4 & (S) & S = S \end{matrix}$

The only correct combination in which the hybridization of one of the S atom is $S p^{2}$ .

Join BYJU'S Learning Program

The correct option is A (III) (i) (R)In K4Ni(CO)4 Ni is in ground state i.e. 3d84s2. While CO is a strong field ligand due to which the configuration of central atom becomes 3d104s0. The 4s and 4p orbitals get hybridized to produce sp3 orbitals.

The correct option is A (III) (i) (R)
In $K_{4} N i (C O)_{4}$ Ni is in ground state i.e. $3 d^{8} 4 s^{2}$ . While CO is a strong field ligand due to which the configuration of central atom becomes $3 d^{10} 4 s^{0}$ .

The 4s and 4p orbitals get hybridized to produce $s p^{3}$ orbitals.