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Question

Column-1 represents the process
Column-2 represents the Δ U for that process and
Column-3 represents the work done expression for that process.
Column I Column 2 Column 3(I)Adiabatic expansion(i)0(P)w=q(II)Irreversible isothermal compression(ii)Positive(Q)w=q(III)Reversible isothermal compression(iii)Negative(R)w=0(IV)Free expansion(iv)q(S)w=ΔU

A gas kept in a 100 L container was allowed to expand in a 5L evacuated container. Which set correctly describes this process?


A
(I) (ii) (P)
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B
(II) (iii) (R)
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C
(IV) (iv) (R)
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D
(III) (i) (Q)
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Solution

The correct option is A (I) (ii) (P)

Since it is a free expansion so work done will be zero i.e. w = 0
From first law of thermodynamics
ΔU=q+w
ΔU=q


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