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Question

Column IColumn II

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Solution

(A) The reduction of primary amine gives alkyl nitrile.
RCNreduction−−−− 1 amine.
(B) Alkyl nitrile reacts with methyl magnesium bromide followed by hydrolysis to form ketone.
RCN(i)CH3MgBr−−−−−−−(ii)H2O ketone.
(C) The hydrolysis of alkyl isocyanide gives primary amine and acid.
RNChydrolysis−−−−− 1 amine, acid.
(D) Aliphatic primary amine reacts with nitrous acid to form primary alcohol and nitrogen.
RNH2HNO2−−− alcohol.

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