(A) The reduction of primary amine gives alkyl nitrile.
RCNreduction−−−−−→ 1∘ amine.
(B) Alkyl nitrile reacts with methyl magnesium bromide followed by hydrolysis to form ketone.
RCN(i)CH3MgBr−−−−−−−−→(ii)H2O ketone.
(C) The hydrolysis of alkyl isocyanide gives primary amine and acid.
RNChydrolysis−−−−−−→ 1∘ amine, acid.
(D) Aliphatic primary amine reacts with nitrous acid to form primary alcohol and nitrogen.
RNH2HNO2−−−−→ alcohol.