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B
1∘<2∘<3∘
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C
2∘<1∘<3∘
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D
1∘<3∘<2∘
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Solution
The correct option is A1∘>2∘>3∘ Among isomeric amines, the primary and secondary amines have highest boiling point due to their large tendency to form hydrogen bonds whereas tertiary amines have the lowest boiling point because of their inability to form hydrogen bond due to the absence of hydrogen atom.
Therefore, the order of boiling piont of isomeric amine is an follows 1∘>2∘>3∘ amines.