Compare the stability of +2 oxidation state for the elements of the first transition series.
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Solution
Oxidations states of first transition metals are shown below: ElementOxidation states
Sc
+3
Ti
+1
+2
+3
+4
V
+1
+2
+3
+4
+5
Cr
+1
+2
+3
+4
+5
+6
Mn
+1
+2
+3
+4
+5
+6
+7
Fe
+1
+2
+3
+4
+5
+6
Co
+1
+2
+3
+4
+5
Ni
+1
+2
+3
+4
Cu
+1
+2
Zn
+2
Sc(II) is virtually unknown, Ti(IV) is more stable than Ti(II). As we move from left to right, the stability of higher oxidation states(sum of s and d electrons) increases in the middle and then abruptly the stability of higher oxidation states decreases in the right side and they show lower oxidation states (+2,+3). Zn only shows +2 oxidation state. Hence, the stability of +2 state increases from left to right in the series.