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Question

Compare the stability of +2 oxidation state for the elements of the first transition series.

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Solution

Oxidations states of first transition metals are shown below:
Element Oxidation states
Sc +3
Ti +1 +2 +3 +4
V +1 +2 +3 +4 +5
Cr +1 +2 +3 +4 +5 +6
Mn +1 +2 +3 +4 +5 +6 +7
Fe +1 +2 +3 +4 +5 +6
Co +1 +2 +3 +4 +5
Ni +1 +2 +3 +4
Cu +1 +2
Zn +2


Sc(II) is virtually unknown, Ti(IV) is more stable than Ti(II). As we move from left to right, the stability of higher oxidation states(sum of s and d electrons) increases in the middle and then abruptly the stability of higher oxidation states decreases in the right side and they show lower oxidation states (+2,+3). Zn only shows +2 oxidation state. Hence, the stability of +2 state increases from left to right in the series.

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